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a variation of the Purex process is being developed to reprocess spent fuel. This modi cation of the Purex process is such that only U and Tc are extracted from the ssion products and TRU nuclei (Np, Pu, Am, Cm). It is called the UREX process (uranium extraction). It is intended to recover .99.9% of the U, .95% of the Tc and leave .99.9% of the TRU nuclei in the acid waste. All chemicals used in the process are converted to gases in subsequent processing to minimize waste. A Purex separation is carried out using 30% TBP in kerosene working on a 1 M HNO3 solution of spent fuel and then acetohydroxamic acid (AHA), an analog of hydroxylamine, is used to reduce Np(VI) to nonextractible Np(V) and to complex Pu(IV) and Np(IV), preventing their extraction. Figures 16.14 and 16.15 show the owsheet for the UREX process and its place in the total, new proposed treatment of spent fuel. Other work on pyrochemical processes involving electrochemical reduction steps in molten salt baths is also underway. Transmutation Transmutation is the term used in connection with waste management to describe a nuclear process in which long-lived nuclides are changed into shorter-lived nuclides by nuclear reactions. Possible sources of bombarding particles are neutrons from reactors or accelerators that have been con gured to produce large neutron uxes, by reactions, such as spallation. Fast neutrons are preferred as the bombarding particle because some of the relevant isotopes of the actinides Np, Am, and Cm are not thermally ssionable. 129I and 99Tc, on the other hand, are readily destroyed in thermal uxes. Transmutation can also be used to destroy plutonium from dismantled nuclear weapons. Of course, the word pdf 417 How to Encode a Tab or Function in a PDF417 in Microsoft Word ...
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